Ni+Pd+Ga and Ni+Pd+in liquid alloys: Enthalpies of formation
Identifieur interne : 000361 ( Main/Exploration ); précédent : 000360; suivant : 000362Ni+Pd+Ga and Ni+Pd+in liquid alloys: Enthalpies of formation
Auteurs : RBID : ISTEX:10973_1991_Article_BF01912198.pdfAbstract
In order to fill the evident gap in the thermodynamic data of nickel-palladium-gallium and nickel-palladium-indium ternary alloys, the enthalpies of formation of these systems in the liquid state have been determined. This was achieved by means of a very high temperature calorimeter (T<1800 K), using the direct drop method, and based on analogous measurements of the respective binary alloys previously published. Complete automation of the calorimeter led to a good precision even at the highest temperatures. The enthalpies of formation of the ternary liquid alloys were measured between 1400 and 1600 K on the whole composition range. As in the limiting binary systems, enthalpies of formation are negative and non temperature dependent at any composition.
DOI: 10.1007/BF01912198
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Escadrille Normandie-Niemen, 13397, Marseille Cedex 13, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Centre de Saint-JérÔme, Sett-UA 1168, Université de Provence, Av. Escadrille Normandie-Niemen, 13397, Marseille Cedex 13</wicri:regionArea><placeName><region type="region" nuts="2">Provence-Alpes-Côte d'Azur</region><settlement type="city">Marseille</settlement></placeName></affiliation><affiliation wicri:level="1"><mods:affiliation>Institute of Inorganic Chemistry, University of Vienna, 42, Wahringerstrasse, 1090, Wien, Austria</mods:affiliation><country xml:lang="fr">Autriche</country><wicri:regionArea>Institute of Inorganic Chemistry, University of Vienna, 42, Wahringerstrasse, 1090, Wien</wicri:regionArea><wicri:noRegion>Wien</wicri:noRegion></affiliation></author><author><name>M. Gaune-Escard</name><affiliation wicri:level="3"><mods:affiliation>Centre de Saint-JérÔme, Sett-UA 1168, Université de Provence, Av. Escadrille Normandie-Niemen, 13397, Marseille Cedex 13, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Centre de Saint-JérÔme, Sett-UA 1168, Université de Provence, Av. Escadrille Normandie-Niemen, 13397, Marseille Cedex 13</wicri:regionArea><placeName><region type="region" nuts="2">Provence-Alpes-Côte d'Azur</region><settlement type="city">Marseille</settlement></placeName></affiliation></author><author><name>J. P. Bros</name><affiliation wicri:level="3"><mods:affiliation>Centre de Saint-JérÔme, Sett-UA 1168, Université de Provence, Av. Escadrille Normandie-Niemen, 13397, Marseille Cedex 13, France</mods:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Centre de Saint-JérÔme, Sett-UA 1168, Université de Provence, Av. Escadrille Normandie-Niemen, 13397, Marseille Cedex 13</wicri:regionArea><placeName><region type="region" nuts="2">Provence-Alpes-Côte d'Azur</region><settlement type="city">Marseille</settlement></placeName></affiliation></author></titleStmt><publicationStmt><idno type="RBID">ISTEX:10973_1991_Article_BF01912198.pdf</idno><date when="1991">1991</date><idno type="doi">10.1007/BF01912198</idno><idno type="wicri:Area/Main/Corpus">000C57</idno><idno type="wicri:Area/Main/Curation">000C57</idno><idno type="wicri:Area/Main/Exploration">000361</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="eng">In order to fill the evident gap in the thermodynamic data of nickel-palladium-gallium and nickel-palladium-indium ternary alloys, the enthalpies of formation of these systems in the liquid state have been determined. This was achieved by means of a very high temperature calorimeter (T<1800 K), using the direct drop method, and based on analogous measurements of the respective binary alloys previously published. Complete automation of the calorimeter led to a good precision even at the highest temperatures. The enthalpies of formation of the ternary liquid alloys were measured between 1400 and 1600 K on the whole composition range. As in the limiting binary systems, enthalpies of formation are negative and non temperature dependent at any composition.</div></front></TEI><mods xsi:schemaLocation="http://www.loc.gov/mods/v3 file:///applis/istex/home/loadistex/home/etc/xsd/mods.xsd" version="3.4" istexId="db7b9dc41367452add3f7fb250a91317e31097be"><titleInfo lang="eng"><title>Ni+Pd+Ga and Ni+Pd+in liquid alloys: Enthalpies of formation</title></titleInfo><name type="personal"><namePart type="given">D.</namePart><namePart type="family">El Allam</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Centre de Saint-JérÔme, Sett-UA 1168, Université de Provence, Av. Escadrille Normandie-Niemen, 13397, Marseille Cedex 13, France</affiliation></name><name type="personal"><namePart type="given">E.</namePart><namePart type="family">Hayer</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Centre de Saint-JérÔme, Sett-UA 1168, Université de Provence, Av. Escadrille Normandie-Niemen, 13397, Marseille Cedex 13, France</affiliation><affiliation>Institute of Inorganic Chemistry, University of Vienna, 42, Wahringerstrasse, 1090, Wien, Austria</affiliation></name><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Gaune-Escard</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Centre de Saint-JérÔme, Sett-UA 1168, Université de Provence, Av. Escadrille Normandie-Niemen, 13397, Marseille Cedex 13, France</affiliation></name><name type="personal"><namePart type="given">J. P.</namePart><namePart type="family">Bros</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Centre de Saint-JérÔme, Sett-UA 1168, Université de Provence, Av. Escadrille Normandie-Niemen, 13397, Marseille Cedex 13, France</affiliation></name><typeOfResource>text</typeOfResource><genre>Original Paper</genre><originInfo><publisher>Kluwer Academic Publishers, Dordrecht</publisher><dateValid encoding="w3cdtf">2005-06-24</dateValid><copyrightDate encoding="w3cdtf">1991</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="eng">In order to fill the evident gap in the thermodynamic data of nickel-palladium-gallium and nickel-palladium-indium ternary alloys, the enthalpies of formation of these systems in the liquid state have been determined. This was achieved by means of a very high temperature calorimeter (T<1800 K), using the direct drop method, and based on analogous measurements of the respective binary alloys previously published. Complete automation of the calorimeter led to a good precision even at the highest temperatures. The enthalpies of formation of the ternary liquid alloys were measured between 1400 and 1600 K on the whole composition range. As in the limiting binary systems, enthalpies of formation are negative and non temperature dependent at any composition.</abstract><abstract lang="ger">Um die Lücke hinsichtlich thermodynamischer Daten von Nickel-Palladium-Gallium und Nickel-Palladium-Indium Legierungen zu füllen, wurden die Bildungsenthalpien dieser ternÄren Systeme im flüssigen Zustand bestimmt. Dies erfolgte mittels eines Kalorimeters für sehr hohe Temperaturen (T<1800 K), unter Verwendung der direkten Einwurfmethode auf der Basis früher veröffentlichter Messungen an den entsprechenden binÄren Systemen. Die Bildungsenthalpien der flüssigen ternÄren Legierungen wurden zwischen 1400 und 1600 K über den gesamten Zusammensetzungsbereich bestimmt. VollstÄndige Automation des Kalorimeters bewirkte hohe PrÄzision selbst bei den höchsten Temperaturen. Wie in den begrenzenden binÄren Systemen sind die Bildungsenthalpien negativ und bei allen Zusammensetzungen nicht temperaturabhÄngig.</abstract><relatedItem type="series"><titleInfo type="abbreviated"><title>Journal of Thermal Analysis</title></titleInfo><titleInfo><title>Journal of thermal analysis</title><partNumber>Year: 1991</partNumber><partNumber>Volume: 37</partNumber><partNumber>Number: 8</partNumber></titleInfo><genre>Archive Journal</genre><originInfo><dateIssued encoding="w3cdtf">1991-08-01</dateIssued><copyrightDate encoding="w3cdtf">1991</copyrightDate></originInfo><subject usage="primary"><topic>Chemistry</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Measurement Science, Instrumentation</topic></subject><identifier type="issn">0022-5215</identifier><identifier type="issn">Electronic: 1572-8943</identifier><identifier type="matrixNumber">10973</identifier><identifier type="local">IssueArticleCount: 42</identifier><recordInfo><recordOrigin>Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest, 1991</recordOrigin></recordInfo></relatedItem><identifier type="doi">10.1007/BF01912198</identifier><identifier type="matrixNumber">Art8</identifier><identifier type="local">BF01912198</identifier><accessCondition type="use and reproduction">MetadataGrant: OpenAccess</accessCondition><accessCondition type="use and reproduction">AbstractGrant: OpenAccess</accessCondition><accessCondition type="restriction on access">BodyPDFGrant: Restricted</accessCondition><accessCondition type="restriction on access">BodyHTMLGrant: Restricted</accessCondition><accessCondition type="restriction on access">BibliographyGrant: Restricted</accessCondition><accessCondition type="restriction on access">ESMGrant: Restricted</accessCondition><part><extent unit="pages"><start>1687</start><end>1695</end></extent></part><recordInfo><recordOrigin>Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest, 1991</recordOrigin><recordIdentifier>10973_1991_Article_BF01912198.pdf</recordIdentifier></recordInfo></mods></record>Pour manipuler ce document sous Unix (Dilib)
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